μ-Propane-1,3-dithiolato-κ4 S,S′:S,S′-bis[dicarbonyl(triphenylphosphane-κP)iron(II)](Fe—Fe)
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چکیده
The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenyl-phosphane ligand and a bis-bidentate dithiol-ate ligand, and also forms an Fe-Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octa-hedral arrangement.
منابع مشابه
Dicarbonyl(pyrazine-1,3-dithiolato-κ2 S,S′)bis(trimethylphosphane-κP)iron(II)
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